CIS-3-AZABICYCLO[3.1.0]HEXANE-2-CARBOXYLIC ACID

CIS-3-AZABICYCLO[3.1.0]HEXANE-2-CARBOXYLIC ACID - Names and Identifiers

Name	(1R,2R,5S)-3-azoniabicyclo[3.1.0]hexane-2-carboxylate
Synonyms	cis-2-Carboxy-3-azabicyclo[3.1.0]hexane CIS-3-AZABICYCLO(3.1.0)HEXANE-2-CARBOXYL 3-AZABICYCLO[3.1.0]HEXANE-2-CARBOXYLIC ACID CIS-3-AZABICYCLO[3.1.0]HEXANE-2-CARBOXYLIC ACID (1R,5S)-3-azabicyclo[3.1.0]hexane-4-carboxylic acid (1S,5R)-3-azabicyclo[3.1.0]hexane-2-carboxylic acid (1R,2R,5S)-3-azoniabicyclo[3.1.0]hexane-2-carboxylate [1-(S)-(1a,2b,5a)]-3-azabicyclo[3.1.0]hexane-2-carboxylic acid
CAS	22255-16-9
InChI	InChI=1/C6H9NO2/c8-6(9)5-4-1-3(4)2-7-5/h3-5,7H,1-2H2,(H,8,9)/t3-,4-,5-/m1/s1

CIS-3-AZABICYCLO[3.1.0]HEXANE-2-CARBOXYLIC ACID - Physico-chemical Properties

Molecular Formula	C6H9NO2
Molar Mass	127.14
Density	1.327±0.06 g/cm3(Predicted)
Melting Point	252-256°C(lit.)
Boling Point	280.3±23.0 °C(Predicted)
Flash Point	123.322°C
Vapor Presure	0.001mmHg at 25°C
pKa	2.38±0.20(Predicted)
Storage Condition	Room Temprature
Refractive Index	1.551

CIS-3-AZABICYCLO[3.1.0]HEXANE-2-CARBOXYLIC ACID - Risk and Safety

Risk Codes	R36/37/38 - Irritating to eyes, respiratory system and skin. R22 - Harmful if swallowed
Safety Description	S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing.
WGK Germany	3
HS Code	29224985
Hazard Class	IRRITANT

CIS-3-AZABICYCLO[3.1.0]HEXANE-2-CARBOXYLIC ACID - Introduction

(1R,2R,5S)-3-azoniabicyclo[3.1.0]hexane-2-carboxylate, also known as ((1R,2R,5S)-3-azoniabicyclo[3.1.0]hexane-2-carboxylate), is an organic compound. The following is a description of its nature, use, formulation and safety information:

Nature:
-Appearance: White or light yellow solid
-Molecular formula: C7H11NO2
-Molecular weight: 141.17g/mol
-Solubility: Soluble in water and polar organic solvents
-Melting Point: about 160-170 ℃

Use:
- (1R,2R,5S)-3-azoniabicyclo[3.1.0]hexane-2-carboxylate is an ionic liquid ligand, commonly used in metal catalyst systems in organic synthesis and catalytic reactions.
-It can form complexes with copper, silver, palladium and other metals, and act as a catalyst in some organic reactions to promote the progress of chemical reactions.

Method:
-A common preparation method is to react 1,3-propanediamine with ethyl formate to produce 3-azabicyclo [3.1.0] hexane-2-carboxylic acid ethyl ester, the (1R,2R,5S)-3-azoniabicyclo[3.1.0]hexane-2-carboxylate is then obtained by hydrolysis.

Safety Information:
- (1R,2R,5S)-3-azoniabicyclo[3.1.0]hexane-2-carboxylate has low toxicity and has no obvious harm to human body under normal circumstances.
-During use and storage, care should be taken to avoid contact with skin and eyes. If accidental contact, rinse immediately with plenty of water.

Last Update：2024-04-10 22:29:15